IB syllabus > acids & bases (sl) > 8.1 

8.1 - Properties of acids and bases


9.1.1: Outline the characteristic properties of acids and bases in aqueous solution. The properties that must be considered are: effects on indicators and reactions of acids with bases, metals and carbonates. Bases which are not hydroxides, such as ammonia, soluble carbonates and hydrogen carbonates, should be included. Alkalis are bases that dissolve in water.


Acids

These are a group of compounds with similar chemical behaviour - i.e. they react in similar ways with other compounds. This is because all acids provide free H+ ions (hydrogen ions) in solution. It is these H+ ions that are actually reacting.

  1. Acids turn indicators characteristic colours (this depends on the indicator) representing.
  2. Acids react with bases to form salt and water (neutralisation). The base may be a metal oxide or a metal hydroxide.
  3. Acids react with carbonates forming a salt, carbon dioxide and water (neutralisation)
  4. Acids react with active metals to form salt and hydrogen (this is not actually a neutralisation reaction although the acid does get used up)

These properties are only expressed in aqueous solution (i.e. a solution in water). The reason for this is that acids can only release their hydrogen ions when they interact with water molecules.

hydrochloric acid
+
water
hydrogen ions
+
chloride ions
HCl
 
(aq)
H+(aq)
 
Cl-(aq)

Consequently, hydrochloric acid provides a solution that contains hydrogen ions and chloride ions - It is only the hydrogen ions that react with bases the chloride ions remain in the solution as spectator ions

Other common strong acids:

  • Sulphuric acid - the solution contains hydrogen ions and sulphate ions
  • Nitric acid - the solution contains hydrogen ions and nitrate ions
  • Phosphoric acid - the solution contains hydrogen ions and phosphate ions

In all cases the acid provides a source of hydrogen ions


Bases

These are the chemical opposites of acids. The property of bases is caused by the presence of OH- (hydroxide) ions in solution.

  • Metal oxides
  • Metal hydroxides
  • Metal carbonates
  • Metal hydrogen carbonates

The bases either produce these hydroxide ions directly by dissolving or they assist the water molecules in breaking up by removing H+ ions from the water. (The situation is a little more complicated than explained as the water is actually in equilibrium with its own ions)


1. The effect of acids and bases on indicators

The colour change depends on the type of indicator used. The most common indicators are universal indicator, litmus indicator and phenolphthalein. The colour changes are:

pH 
Universal indicator
Litmus
Phenolphthalein
Acidic
red
red
colorless
Neutral
green
purple
pink
Basic
purple-blue
blue
red

The degree of acidity or basicity of a solution can be measured by the pH scale. This gives a value proportional to the concentration of H+ ions in the solution

2. Reaction with bases (neutralisation)

Before going over these reactions it is important to understand that bases are the chemical opposites of acids. This means that they contain ions that can neutralise (react with and cancel out) the H+ ions of the acids.

The following types of compounds are classified as bases:

Base
examples
formulae
Metal oxides calcium oxide, magnesium oxide, zinc oxide, iron II oxide CaO, MgO, ZnO, FeO
Metal hydroxides calcium hydroxide, magnesium hydroxide,
sodium hydroxide, potassium hydroxide
Ca(OH)2, Mg(OH)2, NaOH, KOH
Metal carbonates calcium carbonate, magnesium carbonate,
sodium carbonate, potassium carbonate

CaCO3, MgCO3, Na2CO3, K2CO3

Metal hydrogen carbonates sodium hydrogen carbonate, potassium hydrogen carbonate NaHCO3, KHCO3

Example Neutralisation reactions

sulphuric acid
+
magnesium oxide
magnesium sulphate
+
water
   
H2SO4
 
MgO
MgSO4
 
H2O
   
 
 
   
hydrochloric acid
+
calcium oxide
calcium chloride
+
water
   
2HCl
 
CaO
CaCl2
 
H2O
   
 
 
   
sulphuric acid
+
sodium hydroxide
sodium sulphate
+
water
   
H2SO4
 
2NaOH
Na2SO4
 
2H2O
   
 
 
   
hydrochloric acid
+
calcium hydroxide
calcium chloride
+
water
   
2HCl
 
Ca(OH)2
CaCl2
 
2H2O
   
 
 
   
sulphuric acid
+
zinc carbonate
zinc sulphate
+
water
+
carbon dioxide
H2SO4
 
Zn CO3
ZnSO4
 
H2O
 
CO2
 
 
 
hydrochloric acid
+
potassium carbonate
potassium chloride
+
water
+
carbon dioxide
2HCl
 
K2CO3
2KCl
 
H2O
 
CO2
 
 
 
hydrochloric acid
+
sodium hydrogen carbonate
sodium chloride
+
water
+
carbon dioxide
HCl
 
NaHCO3
NaCl
 
H2O
 
CO2

Note: Sulphuric acid always makes salts called sulphates, hydrochloric acid always makes salts called chlorides ( nitric acid makes nitrates, ethanoic acid makes ethanoates - etc.)


Ammonia as a weak base

Ammonia has the molecular formula NH3. It is a pungent (sharp) smelling gas that is used in household cleaners. It is very soluble in water giving a solution of about pH 10.

Ammonia gas dissoves in water to give a solution that behaves as a base in that it neutralises acids producing a salt and water. The reason for this is that the ammonia molecule partially removes some of the hydrogen ions from water leaving the solution with an excess of OH´(hydroxide ) ions. These ions can then react with acids.

ammonia
+
water
ammonium ions
+
hydroxide ions
NH3
 
H2O
NH4+
 
OH-

Examples of ammonia behaving as a base

sulphuric acid
+
ammonia
ammonium sulphate
 
 
H2SO4
 
2NH3
(NH4)2SO4
 
 
 
 
 
hydrochloric acid
+
ammonia
ammonium chloride
 
 
HCl
 
NH3
NH4Cl
 
 
 
 
 
nitric acid
+
ammonia
ammonium nitrate
 
 
HNO3
 
NH3
NH4NO3
 
 
 
 
 
ethanoic acid
+
ammonia
ammonium ethanoate
 
 
CH3COOH
 
NH3
CH3COONH4
 
 

Note: In this case there is no water formed in the reaction. Some textbooks refer to a solution of ammonia in water as 'ammonium hydroxide' solution, NH4OH, (the ions on the right hand side of the equation when it dissolves in water) in which case there will be water formed when it reacts with acids.


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