|
IB
syllabus > acids
& bases (sl) > 8.1
|
|
8.1 - Properties of acids and bases9.1.1: Outline the characteristic properties of acids and bases in aqueous solution. The properties that must be considered are: effects on indicators and reactions of acids with bases, metals and carbonates. Bases which are not hydroxides, such as ammonia, soluble carbonates and hydrogen carbonates, should be included. Alkalis are bases that dissolve in water. AcidsThese are a group of compounds with similar chemical behaviour - i.e. they react in similar ways with other compounds. This is because all acids provide free H+ ions (hydrogen ions) in solution. It is these H+ ions that are actually reacting. |
||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
These properties are only expressed in aqueous solution (i.e. a solution in water). The reason for this is that acids can only release their hydrogen ions when they interact with water molecules.
Consequently, hydrochloric acid provides a solution that contains hydrogen ions and chloride ions - It is only the hydrogen ions that react with bases the chloride ions remain in the solution as spectator ions Other common strong acids:
In all cases the acid provides a source of hydrogen ions BasesThese are the chemical opposites of acids. The property of bases is caused by the presence of OH- (hydroxide) ions in solution.
The bases either produce these hydroxide ions directly by dissolving or they assist the water molecules in breaking up by removing H+ ions from the water. (The situation is a little more complicated than explained as the water is actually in equilibrium with its own ions) 1. The effect of acids and bases on indicatorsThe colour change depends on the type of indicator used. The most common indicators are universal indicator, litmus indicator and phenolphthalein. The colour changes are:
The degree of acidity or basicity of a solution can be measured by the pH scale. This gives a value proportional to the concentration of H+ ions in the solution 2. Reaction with bases (neutralisation)Before going over these reactions it is important to understand that bases are the chemical opposites of acids. This means that they contain ions that can neutralise (react with and cancel out) the H+ ions of the acids. The following types of compounds are classified as bases:
Example Neutralisation reactions
Note: Sulphuric acid always makes salts called sulphates, hydrochloric acid always makes salts called chlorides ( nitric acid makes nitrates, ethanoic acid makes ethanoates - etc.) Ammonia as a weak baseAmmonia has the molecular formula NH3. It is a pungent (sharp) smelling gas that is used in household cleaners. It is very soluble in water giving a solution of about pH 10. Ammonia gas dissoves in water to give a solution that behaves as a base in that it neutralises acids producing a salt and water. The reason for this is that the ammonia molecule partially removes some of the hydrogen ions from water leaving the solution with an excess of OH´(hydroxide ) ions. These ions can then react with acids.
Examples of ammonia behaving as a base
Note: In this case there is no water formed in the reaction. Some textbooks refer to a solution of ammonia in water as 'ammonium hydroxide' solution, NH4OH, (the ions on the right hand side of the equation when it dissolves in water) in which case there will be water formed when it reacts with acids. Useful links |
|
|
||
![]() |
||
|
|
||||||||||
|
Copyright: 2011- IsisSoft Interactive
Publication
|